Valero Energy CorporationNYSE: VLO

Investor Presentation

· MarketScreener

Leading Producer of Liquid

Transportation Fuels Advancing the Future of Energy

• With Capital Discipline, Innovation and Unmatched Execution

C A P I TA L D I S C I P L I N E I N N OVAT I O N

U N M ATC H E D E X EC U T I O N



I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6



REFINING

W O R L D ' S P R E M I E R I N D E P E N D E N T

R E F I N E R



LEADING PROFITABLE PRODUCER OF LOW-CARBON TRANSPORTATION FUELS

RENEWABLE DIESEL

D I V E R S I F Y I N G I N T O H I G H E R G R O W T H , H I G H E R M A R G I N S A F

ETHANOL

D E V E L O P I N G P R O J E C T S T O C R E A T E A H I G H E R V A L U E E T H A N O L P R O D U C T

GROWTH PROJECTS FOCUSED ON COST CONTROL, OPTIMIZATION AND MARGIN EXPANSION

14

refineries

lowest cost producer

3.0

million barrels per day of high-complexity throughput capacity

advantaged refining and logistics assets well positioned for feedstock and product optimization

ratable wholesale supply of

>1.5 million barrels per day or

over 50% of our light products

Renewable Diesel

Refining

PREMIER REFINING PORTFOLIO INDEPENDENTLY FOUND TO BE RESILIENT EVEN IN A CARBON-CONSTRAINED SCENARIO(1)



PROFITABLE, HIGH RETURN PROJECTS TARGETING GROWING LOW-CARBON MARKETS

Ethanol

Midstream

Wholesale

up to

billion gallons per

up to

million gallons

low-carbon intensity renewable products

up to

reduction in

1.2

year of liquid

renewable fuels

235

per year of SAF

produced primarily from recycled animal

fats, used cooking oil, and inedible corn oil

80% life cycle GHG

emissions

Best-in-class



DIAMOND GREEN DIESEL

(DGD)

SUSTAINABLE AVIATION FUEL (SAF) PROJECT COMPLETED IN 4Q 2024

producer of fuels

and products that



DEVELOPING ECONOMIC PROJECTS TO FURTHER REDUCE CARBON INTENSITY

are essential to

ethanol

billion gallons per year

high-octane renewable

at least

reduction in

existing logistics assets well

modern life

12 plants

1.7

production capacity

fuel with lower CO2emissions

30% life cycle GHG

emissions

positioned to support export growth



PURSUING REDUCTIONS IN CARBON INTENSITY THROUGH CARBON SEQUESTRATION

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

(1) HSB Solomon Associates concluded that under the IEA's NZE 2050 Scenario, our overall refining portfolio would be resilient. Pages 4-5

3

and 29-30 of our 2022 TCFD Report contain additional information on Solomon's analysis.





Demonstrated commitment to capital discipline, innovation and unmatched execution

Operations

Earnings Growth

Capital Discipline

Unmatched Execution with a Proven History of Operations Excellence

  • The lowest cash operating cost among peer group while maintaining top quartile operating performance

  • Safe, reliable, environmentally responsible operations have driven higher profitability and lower volatility through multiple commodity cycles

  • Applying our liquid fuels manufacturing expertise to optimize our integrated low-carbon fuels businesses

    Growth Through Innovation

  • Refining growth projects focused on operating cost control, optimization and margin improvement

  • Leveraging our global liquid fuels platform to expand our long-term competitive advantage with investments in economic low-carbon projects

  • 25% after-tax IRR hurdle rate for growth projects

    Demonstrated Commitment to Stockholders

  • Disciplined capital allocation delivering peer-leading free cash flow yield and returns to stockholders across margin cycles

  • Delivered on our annual payout ratio commitment every year under current management (since 2014)

    • Average payout ratio of 70% since 2014 (59% excluding 2020)

    • Reduced our shares outstanding by approximately 42% since 2014

  • 15% average annual Return on

Invested Capital (ROIC) since 2014

Steadfast in the

execution of our strategy, pursuing

excellence in

operations,

investing for

earnings growth with lower volatility and honoring our

commitment to stockholder returns

Comprehensive liquid fuels strategy underpinned by excellence in operations, disciplined capital allocation and a commitment to shareholder returns

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

See slides 41-43 for notes regarding this slide. See slides 44-59 for non-GAAP disclosures.

4

Peer group includes PSX, MPC, DINO, and PBF.



SIZE, SCALE AND GLOBAL REACH

EXTENSIVE CONNECTIVITY AND GLOBAL OPTIMIZATION

LOWEST COST PRODUCER

RELIABLE TOP QUARTILE OPERATIONS

DISCIPLINED INVESTMENTS

GROWTH WITH LOWER VOLATILITY

PREMIER REFINING PORTFOLIO

INDEPENDENTLY FOUND TO BE RESILIENT EVEN IN A CARBON-CONSTRAINED SCENARIO(1)

SIZE, SCALE AND GLOBAL REACH

Long-term, sustainable competitive

high complexity coastal system with extensive connectivity to inland and imported crudes

operational flexibility to process a wide range of feedstocks

ratable wholesale supply of

>1.5 million barrels per day or over 50% of our light products

global operations support optimization of

product exports

one of the largest light products importers into Mexico

advantage

Free Cash Flow

Average Free Cash Flow 2012 - 2025

LOWEST COST PRODUCER WHILE ACHIEVING RELIABLE TOP QUARTILE OPERATIONS

Peer Range

$3,594 10%

safety and reliability are imperative

for profitability

2025 was our best year ever for Employee

and Contractor Safety, Environmental

Performance and Mechanical Availability

access to cheap natural gas and a deep pool

of skilled labor in the U.S. Gulf Coast

INVESTMENTS IN EFFICIENCY, MARKET EXPANSION AND HIGHER MARGIN CAPTURE

reducing cost and improving margin capture

  • Wilmington and Pembroke cogens

  • St. Charles and Port Arthur hydrocrackers

  • Port Arthur coker

  • Houston and St. Charles alkylation units

    improving feedstock flexibility, cost and crude quality

  • Diamond, Sunrise and Red River pipelines

  • Connectivity in Corpus Christi

  • Line 9 into Quebec

  • Houston and Corpus Christi toppers

    growing market share into higher netback markets

  • Central Texas pipelines and terminals

  • Pasadena terminal

  • Expansion into Latin America with investments in Mexico and Peru

$0

($ in millions)

0%

(% of Average

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

Source: Bloomberg and company reports. See slides 41-43 for notes regarding this slide. See slides 44-59 for non-GAAP disclosures. Peer group includes PSX, MPC, DINO, and PBF.

(1) HSB Solomon Associates concluded that under the IEA's NZE 2050 Scenario, our overall refining portfolio would be resilient. Pages 4-5

and 29-30 of our 2022 TCFD Report contain additional information on Solomon's analysis.

Market Cap)

5





High operational and supply flexibility coupled with low cost operations are driving profitability through-cycle

$9.00

Refining Segment Cash Operating Expenses

Per Barrel of Throughput

(excludes turnaround and D&A expenses)



Peer Range





$18.00

Refining Segment Adjusted EBITDA

Per Barrel of Throughput

(excludes turnaround expenses)



Peer Range

$7.50



2014

2015

2016

2017

2018

2019

2020

2021

2022

2023

2024

2025

$3.00

-$4.00

$3.00



10-Year Average

2014

2015

2016

2017

2018

2019

2020

2021

2022

2023

2024

2025

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

See slides 41-43 for notes regarding this slide.



See slides 44-59 for non-GAAP disclosures. 6

Peer group includes PSX, MPC, DINO, and PBF.



Improving the margin capability of our portfolio through disciplined refining optimization and strategic growth projects

St. Charles Fluid Catalytic Cracker (FCC) Optimization

  • Project is estimated to cost $230 million and expected to be completed in the second half of 2026

    − Expected to return >25% after-tax IRR at mid-cycle pricing assumptions

  • Install a new compressor and upgrade existing equipment

    − Incremental 15 mbpd FCC rate with residual feedstock

    − Improves product yields to increase propylene production and fill downstream Alkylation unit capacity, producing an incremental 6 mbpd of high value alkylate

    Select Refining Optimization and Strategic Growth Projects

    ($ in millions)

    Optimization and Strategic Projects

    (in-service date)

    Project Description

    Annual EBITDA Estimate

    (at FID)

    Large Capital Projects (≥$300, >25% unlevered after-tax IRR at FID)

    Port Arthur Coker (2Q23)

    See slide 26

    $325

    Houston Alky (4Q19)

    See slide 27

    $100

    Small Capital Projects (≤$50, 30% to 65% unlevered after-tax IRR at FID)

    Texas City Crude Flexibility (1Q17)

    See slide 41

    $30

    St. Charles Alky (4Q20) See slide 27 $150

    Incremental Feedstock & Products (MBPD)

    Feedstocks

    Low Sulfur Resid

    15

    Products

    Gasoline

    8

    Alkylate

    6

    Propylene

    3

    Port Arthur Butane Rail Rack (3Q17)

    See slide 41

    $10

    St. Charles Gasoline Blender (2Q17)

    See slide 41

    $15



    I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6 See slides 41-43 for notes regarding this slide. 7



    Leadership in low-carbon renewable fuels underpinned by high economic returns

    DGD Renewable Fuels Capacity

    (million gallons per year)

    20

    Renewable Naphtha

    Sustainable Aviation Fuel (SAF) Renewable Diesel

    30

    730

    275

    290

    15

    160

    410

935

235

235

50

235

470

115



1,220

1,220

Renewable Diesel Realized Cash Flow Profile

($ in millions)

$2,071 million cumulative Capex(1)

Cumulative EBITDA

DGD 1 Cumulative Capex

DGD 2 Cumulative Capex

DGD 3 Cumulative Capex

Net Cumulative Cash Flow (EBITDA less Capex)

$3,005 million cumulative EBITDA(1)

$3,100

2013

DGD 1

2018

DGD 1

2020

DGD 1

2021

DGD 2

2022

DGD 3

4Q24 DGD

2023

4Q24

($2,100)

2011

2012

2013

2014

2015

2016

2017

2018

2019

2020

2021

2022

2023

2024

2025

St. Charles

Expansion

Optimization St. Charles

Port Arthur Port Arthur

SAF

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

See slides 44-59 for non-GAAP disclosures.

(1) Diamond Green Diesel EBITDA and Capex reflects Valero's 50% share.

8





Expanding our competitive advantage with sustainable aviation fuel (SAF) DGD Port Arthur SAF Project

  • Large-scale SAF project at the DGD Port Arthur plant was completed in the fourth quarter of 2024

    − The plant has the capability to upgrade up to 50% of its current renewable diesel production capacity to SAF, or ~235 million gallons per year

    − The project cost was $315 million, with half of that attributable to Valero

    − Project included a heater, a fractionation unit to separate the SAF and renewable diesel product streams, and additional product tankage

  • Project is expected to exceed our minimum return threshold of an after-tax IRR of 25%

    − SAF supports airlines' compliance with global mandates and reduces their offset obligations



    I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

    See slides 41-43 for notes regarding this slide.

    9





    Ethanol segment leverages low-cost operations and scale to capture margin upside



    Operations Outlook

    U.S. Fuel Ethanol Exports

    (mbpd)

  • 12 plants with 1.7 billion gallons annual production capacity

    • Efficient plants with scale, located in

      the corn belt

    • Operational best practices transferred from refining

    • Increasing production of lower carbon intensity fiber cellulosic ethanol

  • Cost advantaged versus the industry

    Strong free cash flow profile under VLO ownership

  • Ethanol will remain a significant part of the global fuel mix

  • Global renewable fuel mandates should drive export growth, such as Canada's new CFR regulation

  • Carbon reduction programs providing

    economic incentives:

    • 45Q Tax Credit provides economic incentive for CO2sequestration

    • LCFS and D3 RINS provide higher value

      for the lower carbon intensity ethanol

    • Operational efficiency allows capture of 45Z Tax Credit through 2029

Rest of Industry Valero

125

112

91

96

43

25

94

88

88

32

76

20

82

19

24

19

13

26

54

21

87

93

99

72

77

64

69

68

51

64

61



142

Average Ethanol Segment Adjusted EBITDA per gallon (2009-2025)

$0.02

$0.26

Average Sustaining Capex per gallon

(2009-2025)

2015 2016 2017 2018 2019 2020 2021 2022 2023 2024 2025



I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

Totals may not sum due to rounding.



Source: U.S. Energy Information Agency (EIA) through December 2025. 10

See slides 41-43 for notes regarding this slide. See slides 44-59 for non-GAAP disclosures.



Refining business generates significant cash to support growth and stockholder returns

Sources and Uses of Cash - Cumulative: December 31, 2014 to December 31, 2025

($ in billions)

$3.7

Sources of Cash

Uses of Cash

$4.7

$66.9

($24.6)

Sustaining capital ($16.1)

Growth capital ($7.3) Acquisitions ($1.2)

($38.6)

Dividends ($15.1)

Share Repurchases ($23.5)

($2.7)

Cash and Cash Equivalents

December 31, 2014

Net Cash Provided by

Operating Activities

Capital Investments Stockholder Returns Other

Attributable to Valero

and Acquisitions

Cash and Cash Equivalents

December 31, 2025

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

See slides 44-59 for non-GAAP disclosures. Totals may not sum due to rounding.

11





Disciplined capital allocation is a constant in our strategy

1 Maintain a Strong Balance Sheet

2 Non-discretionary

3 Discretionary

Share Repurchases

Commitment to a through-cycle minimum annual payout ratio of 40% to 50% of adjusted net cash provided by operating activities

  • Share repurchase program consists of ratable and opportunistic purchases

•

•

Acquisitions

  • Evaluate versus alternative uses of cash

Growth Capex

25% after-tax IRR hurdle rate for projects

Refining projects focused on operating cost control, market expansion and margin improvement

Economic low-carbon fuels expansion

•

•

Dividend

  • Commitment to stockholders

  • Targeting a sustainable and growing dividend with a dividend yield that is at the high end of our peer group

Sustaining Capex

  • Targeting approximately $1.4 billion in 2026

  • Key to safe and reliable operations

Target 20% to 30% net debt-to-cap ratio

Maintain an investment grade credit rating

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

See slides 41-43 for notes regarding this slide.

12





Steady investments to maintain our asset base and enhance the margin capability of our portfolio

Growth capital

investments underpinned by a 25% unlevered

after-tax IRR hurdle rate

$3.4

Annual Capital Investments Attributable to Valero

($ in billions)

$2.8 $2.7

$2.6 $2.6

$2.4

~100%

Sustaining Capex as a percentage of Depreciation and Amortization

Executing

FCC Optimization

project at St. Charles

Completed

Port Arthur Coker

$1.5

$1.8

$1.4

$1.5

$1.0

$2.0

$2.2

$0.9

$0.7

$0.9

$2.0 $1.8

$2.3

$0.9

$1.8

$1.9

$1.8

$1.7

Completed

Alkylation Units

at St. Charles & Houston

$1.4

$1.2

$1.5

$0.6

$1.4

$1.3

$1.9

$1.7

$0.9

$1.1

$0.7

$1.1

$1.3

$0.3

$1.4

$0.3

$1.6

$0.2

$1.6

$1.4

$0.3

2012

Steady investments to improve portfolio efficiency

53%

2025

Completed

Topping Capacity

at Corpus Christi & Houston

Completed

Hydrocracking Units

at St. Charles & Port Arthur

Completed Renewable Diesel production

Completed

Sustainable Aviation

Sustaining capital investments includes costs for turnarounds and catalysts and projects to comply with regulatory compliance. Growth capital investments includes joint-venture investments but excludes acquisitions. Sustaining

and growth excludes 50% of DGD's sustaining and growth capex attributable to the other joint venture member and those related to other variable interest entities. See slides 44-59 for non-GAAP disclosures. Totals may not sum due to rounding.

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

Fuel (SAF)

13

5-year average:

(2021-2025)

Sustaining

$1.4

Growth

$0.5





Delivering on our commitment of cash returns to stockholders

Share Repurchases Dividends

Share Repurchases Dividends

Stockholder Returns(1) ($ in billions)

$1.5

$5.2

$4.6

$6.1

$6.6

Payout Ratio(1)

78%

65% 63%

54%

56%

60%

67%

47%

50%

45%

30% 31%

11%

184%

$0.6

$0.3

$0.5

$0.9

$1.4

$0.6

$1.3

$1.9

$0.8

$2.8

$3.7

$1.1

$1.3

$2.4

$1.2

$1.4

$2.6

$3.1

$1.7

$1.4

$1.5

$0.8

$2.3

$1.6

$0.2

$1.8

$1.6

$1.6

$1.6

$4.3

$4.0

$0.4

$1.4

$1.4

$2.6

$2.9

2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 2022 2023 2024 2025

2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 2022 2023 2024 2025

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

See slides 41-43 for notes regarding this slide. See slides 44-59 for non-GAAP disclosures. Totals may not sum due to rounding.



(1) Effective 2023, share repurchases include a 1% excise tax. Accordingly, 2023, 2024 and 2025 include $52 million, $28 million and $26 14

million of excise tax, respectively.



Delivering cash returns through sustainable dividend growth and discretionary share repurchases

552

536

514

473

452

434

46% reduction in shares outstanding since 2012

418

409 408

409

372

333

27% reduction in shares outstanding since 2021

315

299



Shares Outstanding (in millions)

Annual Dividend Per Share

$4.52

$4.28

$4.08

$3.92 $3.92 $3.92

$3.60

$3.20

$2.80

$2.40

$1.70

$1.05

$0.85

$0.65

Dividend Per Share CAGR since 2012 vs.

Peers(2)(3)

Peer Range(3)

15%

0%



$4.80

2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 2022 2023 2024 2025 (1)

2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 2022 2023 2024 2025 2026(2)

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

(1) 2025 shares outstanding as of December 31, 2025.



(2) 2026 dividend per share annualized based on most recent quarterly dividend. 15

(3) Peer group includes PSX, MPC, DINO, and PBF.



Demonstrated lower volatility in earnings and free cash flow

Average Free Cash Flow 2012 - 2025

Peer Range

10%

Volatility 2012 - 2025

S&P 500 Free Cash Return Profile 2012 - 2025

VLO

Financials 6%

10%

Valero has demonstrated

higher

$3,594

$0 0%

Health Care Information Technology

Refining Peers Communication Services

Industrials Consumer Staples Consumer Discretionary

Materials

5% average free

5% cash flow and

5% lower

5% volatility in

5% earnings

5%

4%

4%

110% 113%

72%

$ in Millions % of Average

Market Cap

Free Cash

Flow

Adjusted EPS

EBITDA

16

Oil Majors

4%

Energy

4%

Real Estate

1%

Utilities

-3%

Average TTM Free Cash Flow as a % of Average Market Cap

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

Source: Bloomberg and company reports. Refining peers include PSX, MPC, DINO, and PBF. See slides 41-43 for notes regarding this slide. See slides 44-59 for non-GAAP disclosures.





Disciplined allocation of capital and execution of our strategy is delivering higher return on investment

ROIC Including Amounts Attributable to the Other Joint Venture Members

Adjusted Return on Equity (ROE) Attributable to Valero

20%

14%

Peer Range

19%

30%

16%

Peer Range

24%

Premier Refining portfolio independently found to be resilient even in a carbon-constrained scenario

Lowest cost producer

Growth capital investments underpinned by a 25% unlevered after-tax IRR hurdle rate

5%

10-Year Average 5-Year Average

0%

10-Year Average 5-Year Average

Commitment to a through-cycle minimum annual payout ratio of 40% to 50%

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

See slides 44-59 for non-GAAP disclosures. Peers include PSX, MPC, DINO, and PBF. 17





Appendix contents

Topic

Slide

Global scale with concentration in advantaged U.S. Gulf Coast

19

Crude supply advantage in the U.S. Gulf Coast and Mid-Continent

20

Global optimization of operations, ratable global wholesale supply and product exports

21-24

Completed projects

25-28

U.S. natural gas cost advantages

29

Reliability and safety

30

Low-carbon fuels

31-33

Refining capacity and Nelson Complexity Index

34

Valero's logistics assets

35

Governance and engagement

36-38

Electric vehicle (EV) emissions

39-40

Notes

41-43

Non-GAAP disclosures

44-59

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6



18



Global scale with concentration in advantaged U.S. Gulf Coast

2.5 mmbpd Refining Capacity

(mbpd, % of overall crude capacity)

U.S. West Coast

CANADA

North Atlantic

U.S. Mid-Continent

440

18%

461

18%

1,534

61%

85, 3%

U.S. Gulf Coast

UNITED

STATES

IRELAND

UNITED KINGDOM

1,534

Gulf Coast Refining Capacity(1)

(mbpd, % of overall crude capacity)

PERU

61%

1,248

42%

541

27%

185

18%

0

WHOLESALE MARKETING PRESENCE BRANDED WHOLESALE PRESENCE

VALERO REFINERIES

VLO MPC PSX PBF DINO

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

MEXICO

(1) CDU capacity from EIA data and company reports.

See slide 35 for Valero's capacity and Nelson

complexity by refinery.

(1) CDU capacity from EIA data and company reports. See slide 34 for Valero's capacity and Nelson complexity by refinery.

VALERO ETHANOL PLANTS VALERO TERMINALS DIAMOND GREEN DIESEL

U.S. RENEWABLE DIESEL WHOLESALE PRESENCE

PIPELINES



19



Crude supply advantage in the U.S. Gulf Coast and Mid-Continent

Local Crude Gathering

McKee

Cushing-McKee Connection

Childress Station

To St. James

Hewitt

Cushing

Ardmore

Diamond Pipeline

Collierville

Crude System

Memphis

Valero U.S. Gulf Coast Feedstock Ranges



(quarterly averages)

54%

McCamey

Midland

Colorado City

Eagle Ford:

Harvest Pipeline EOGPipeline Permian:

Cactus Pipeline

Gray Oak

Local Crude Gathering

Wichita Falls

Wasson

To Nederland

Three Rivers

34% 34%

17%

17%

Sunoco

Oakville Terminal

23%

Taking advantage of Permian crude with investments in Corpus Christi

Corpus Christi West and East

Cactus Cactus II

Gray Oak

6%

Heavy Sour Medium / Light

Sour

6%

Sweet Residuals

Sunoco North Beach

EPIC

Blue lines and terminals represent Valero ownership interest.

I N V E S T O R P R E S E N T A T I O N | A P R I L 2 0 2 6

Valero's refineries have operational flexibility to process a wide range of feedstocks, along with access to a deep pool of skilled labor on the U.S. Gulf Coast

Crude Export Dock

Crude Export Tankage

Source: VLO quarterly data from 2012 through 2025. See slides 41-43 for notes regarding this slide.

20



I N V E S T O R P R E S E N TAT I O N | A P R I L 2 0 2 6

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