Slide 1: Cleaner Portfolio and Applications
Cleaner Portfolio and Applications Stephanie Zublick Global Product Manager Cleaning and Acid Pickling Applications CONFIDENTIAL
Slide 2: Cleaner Applications
Cleaner Applications CONFIDENTIAL, DO NOT DISTRIBUTE 2 ©2021 Quaker Houghton. All Rights Reserved
Slide 3: Metalworking Process Cleaners
Metalworking Process Cleaners Forging/Casting/ Surface Rough Machining Cleaning Heat Treatment Finishing Cleaning Protection Steel Slabs or Bars Treatment CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 3
Slide 4: Cleaner Selection Criteria
Cleaner Selection Criteria Solvent or Water Source/Quality Washer Type Metallurgy Previous Subsequent Operations/ Operations Soil Approvals, Regulations and Waste Treatment CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 4
Slide 5: Cleaner Selection Criteria
Cleaner Selection Criteria Water Quality/ Source Metallurgy/ Material Compatibility • Deionized water • Considerations for both the part • Susceptible to excess foaming and/or being cleaned and the cleaning corrosion equipment • Soft Water • Steel, Aluminum, Copper, Brass, • Incorrect cleaner choice
Slide 6: Soil and Previous Operation
Soil and Previous Operation Chemical compatibility between the soil Forming Fluids/ Heavy Duty Cutting being removed and the cleaner is fluids desired to optimize cleaning • High alkaline cleaners; solvent performance to reduce: cleaners • Cleaning contact times Heat Treatment fluids/ Medium • Chemi
Slide 7: Subsequent Processes
Subsequent Processes • Rinsing • Storage • Cleaner may need to provide extended corrosion protection • Surface Treatment • Must be compatible with conversion coating or anodizing process; prepare surface • Heat Treatment • Critical to be residue free • Corrosion Preventative or Coating Application •
Slide 8: Washer Types
Washer Types • Spray • Most widely used • Higher throughput • Longer sump life • Many configurations • Immersion/Ultrasonics • Good cleaning for difficult geometry • Builds up soils • Slower process • Maintenance/Floor Cleaning CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 9 ©2019 Quaker Ho
Slide 9: Spray Cleaning
Spray Cleaning CONFIDENTIAL, DO NOT DISTRIBUTE 10 ©2021 Quaker Houghton. All Rights Reserved
Slide 10: Aqueous Spray Process Cleaners
Aqueous Spray Process Cleaners • Advantages • Low foaming • Suitable for Multi-metal • Biostable • Provides Mild to extended Rust protection • Oil rejection • Disadvantages • Requires good impingement • Needs proper part/spray orientation • Rinse system can affect rust protection CONFIDENTIAL, FOR I
Slide 11: Conveyor type washer
Conveyor type washer Parts loaded on conveyor lines and are carried through the washer Large footprint, allows continuous cleaning, separated stages, wash rinse , RP, orientation and stacking important CONFIDENTIAL, DO NOT DISTRIBUTE 12 ©2019 Quaker Houghton. All Rights Reserved
Slide 12: Clamshell washers
Clamshell washers • Top loading washer • Batch cleaning, trays or baskets CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 13 ©2019 Quaker Houghton. All Rights Reserved
Slide 13: Spray cabinet washers
Spray cabinet washers Front loading unit Allows hanging parts, and larger components CONFIDENTIAL, DO NOT DISTRIBUTE 14 ©2019 Quaker Houghton. All Rights Reserved
Slide 14: Drum washer
Drum washer Internal spiral unit to turn parts as they move through the washer Good for small flat parts that may stick together Size and weight limitations due to parts moving during wash cycle CONFIDENTIAL, DO NOT DISTRIBUTE 15 ©2019 Quaker Houghton. All Rights Reserved
Slide 15: Immersion Cleaning
Immersion Cleaning CONFIDENTIAL, DO NOT DISTRIBUTE 16 ©2019 Quaker Houghton. All Rights Reserved
Slide 16: Immersion washers
Immersion washers • Conventional immersion - Basic soak tank to allow cleaners to dissolve and disperse soils • Jetted immersion - Combines the impingement effect of spray washers by having submerged jets to help remove soil • Agi-lift - Allows stacked or baskets that cycle up and down to help remov
Slide 17: Soak/Immersion Cleaners
Soak/Immersion Cleaners • Advantages • Can be Multi-metal • Good detergency • Good for difficult part geometry • Disadvantages • High soil loading • Shorter system life • Needs adequate agitation • Possible foam issues CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 18 ©2019 Quaker Houghton.
Slide 18: Soak Washer
Soak Washer ©2019 CONFIDENTIAL, Quaker FOR Houghton. INTERNAL All Rights USE ONLY, Reserved DO NOT DISTRIBUTE 19
Slide 19: Other Cleaning Applications
Other Cleaning Applications CONFIDENTIAL, DO NOT DISTRIBUTE 20 ©2019 Quaker Houghton. All Rights Reserved
Slide 20: Maintenance Cleaners
Maintenance Cleaners • Properties • High detergency • General purpose maintenance cleaning • Moderate to high foam • Good solvency for cutting grease • Uses • Floor scrubbers • Manual bucket cleaning • General maintenance cleaning CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 21 ©2021 Quake
Slide 21: System Cleaners
System Cleaners • Designed as support products to the Metal Working product lines for routine maintenance of central coolant/ cleaner systems. • Used as a trial enabler- given to customers to clean out their machines and central systems to help aid success of Fluid Trial- remove the competitor • For
Slide 22: Basic Chemistry
Basic Chemistry CONFIDENTIAL, DO NOT DISTRIBUTE 23 ©2019 Quaker Houghton. All Rights Reserved
Slide 23: General Composition
General Composition • Water • Alkalinity • Builders • Corrosion Inhibitors • Chelating/Sequestering Agents • Surfactants/Wetting Agents • Additives CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 24 ©2019 Quaker Houghton. All Rights Reserved
Slide 24: Alkalinity
Alkalinity • Caustic – KOH, NAOH. Allows heavy duty cleaning for difficult soils such as stearates, greases, varnishes, etc. KOH based product show better product stability and solubility in use. NAOH typically used where cost is an issue. • Carbonate – sodium and potassium. Provides alkalinity for
Slide 25: Builders
Builders • Phosphate Salts • Aids in water softening and provide some detergency • TSP, TKPP, STPP • Gluconates • Chelates metals in solution to help stabilize cleaners and maintain cleaning ability • Gluconic acid, Sodium gluconate, Sodium heptagluconate • Silicates • Provides additional cleaning a
Slide 26: Corrosion Inhibitors
Corrosion Inhibitors • Ferrous • Carboxylate salts • Sodium Nitrite • Phosphate esters • Borate salts • Yellow Metals • Benzotriazole/ Tolyltriazole • Aluminum • Phosphate esters • Silicates CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 27 ©2019 Quaker Houghton. All Rights Reserved
Slide 27: Chelating/Sequestering Agents
Chelating/Sequestering Agents • Ethylenediamine tetra-acetic acid (EDTA) • Most effective for hard water stability, Down sides are corrosion, and waste treatment issues. • Citric acid • Light chelate for iron, limited performance for hardness • Polyacrylic acid • Good option for hardness control in
Slide 28: Surfactants / wetting agents
Surfactants / wetting agents • Nonionics • Neutral charged • EO/PO based materials typically alcohols • Most frequent surfactant. • Can foam or control foam • Good emulsifier for oils and greases • Anionics • Negative charged • Alkyl benzene sulfonate, phosphate esters • High foaming • More effectiv
Slide 29: Specialty Additives
Specialty Additives • Solvents • Co-emulsifiers, improves solvency, grease cutting • Glycol Ethers, D-limonene, Aliphatic hydrocarbons • Hydrotropes • Stabilizes formulations allows use of limited water-soluble materials • Short chain fatty acids, Anionic surfactants. • Biocides • Rarely used • Stan
Slide 30: Cleaner Design
Cleaner Design • Customer focused design • Stay connected to trends in metalworking fluid development R&D Testing Parameters • Cleanliness Testing- spray and/or immersion • Foaming Profile- with and without soil; recirculation; high pressure • Surface Tension • Contact angle • Water hardness • Oil R
Slide 31: Product Maintenance
Product Maintenance CONFIDENTIAL, DO NOT DISTRIBUTE 32 ©2019 Quaker Houghton. All Rights Reserved
Slide 32: Key Parameters To Monitor
Key Parameters To Monitor • pH - check daily • Corrosion control • The higher the alkalinity, the fewer problems with steel corrosion • Biological control • Bacteria and fungus grow faster below pH of 9.0 • High pH can lead to excess soap formation, increased foam CONFIDENTIAL, FOR INTERNAL USE ONLY
Slide 33: Key Parameters To Monitor
Key Parameters To Monitor • Concentration - check daily • Refractometer does not work when tramp oil is present • Titration methods - burette or test kits • Low concentration - possible rust, risk of bacteria and fungus, incomplete cleaning • High concentration - more rinsing needed, excess cost, ca
Slide 34: Key Parameters To Monitor
Key Parameters To Monitor Tramp oil - check weekly • Increased Soil Load • Causes decreased free alkalinity to achieve cleaning • Dirty cleaner can redeposit soil on the part • Can result in excessive foaming in spray applications • Use filtration and splitting L: Fresh cleaner M: Emulsified oil con
Slide 35: Key Parameters To Monitor
Key Parameters To Monitor • Biological - check weekly • Biostablity issues occur when: • Concentration is low • pH is low • Previous soil contamination • Build-up in lines and overhead areas • Biostable cleaners • Complete system cleanouts may be necessary from time to time • Keep tramp oil concentr
Slide 36: Key Parameters To Monitor
Key Parameters To Monitor • Hardness, Chlorides, Sulfates - when possible • Will occur as system ages and solids build up from water additions • Higher temperatures accelerates increased levels • Reduced cleaner performance • More residue on parts • Possible rust issues • Solids build up in washer •
Slide 37: Hardness Effect on Corrosion
Hardness Effect on Corrosion Hardness (ppm) Cleaner DI 100 200 300 400 Concentration 3% (v/v) 4% (v/v) 5% (v/v) 6% (v/v) 7% (v/v) CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 38 ©2019 Quaker Houghton. All Rights Reserved
Slide 38: Troubleshooting
Troubleshooting CONFIDENTIAL, DO NOT DISTRIBUTE 39 ©2019 Quaker Houghton. All Rights Reserved
Slide 39: Determination of Part Cleanliness
Determination of Part Cleanliness Visual inspection/ Carbon analysis Tape/ adhesion test Surface Tension UV Fluorescence Wipe Test measurement- (CleanoSpector) Dynes, water break CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 40 ©2019 Quaker Houghton. All Rights Reserved
Slide 40: Common issues with cleaning failures
Common issues with cleaning failures • Review washer history • Process controls • Pressures • Temperature • Dwell time • Fluid Controls • pH • Concentration • Bios • Hardness • Chlorides • Tramp oil CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 41 ©2019 Quaker Houghton. All Rights Reserved
Slide 41: Common issues with cleaning failures
Common issues with cleaning failures • Different incoming soil • Additional types of lubricants • Different vendor sources • Changes to lubricant formulation • Increased throughput • Less quiet time • Increased rate of cleaner depletion • Increased cleaner contamination CONFIDENTIAL, FOR INTERNAL US
Slide 42: Common issues with cleaning failures
Common issues with cleaning failures • Mechanical issues • Skimmers/filtration not functional • Plugged nozzles/ misalignment • Dirty washer walls/ceilings • Air leaks • Filtration materials, avoid polypropylene • Water quality • Raw water • Water purification failure CONFIDENTIAL, FOR INTERNAL USE
Slide 43: Common issues with cleaning failures
Common issues with cleaning failures • Part geometry • Blind holes • Recessed areas • Trapped fluid CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 44 ©2019 Quaker Houghton. All Rights Reserved
Slide 44: CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE
CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 45 ©2019 Quaker Houghton. All Rights Reserved
Slide 45: Break
Break CONFIDENTIAL, DO NOT DISTRIBUTE 46 ©2021 Quaker Houghton. All Rights Reserved
Slide 46: Metalworking Cleaner Key Portfolio
Metalworking Cleaner Key Portfolio CONFIDENTIAL, DO NOT DISTRIBUTE 47 ©2021 Quaker Houghton. All Rights Reserved
Slide 47: Global MW Cleaner Portfolio
Global MW Cleaner Portfolio Quakerclean 624 CP Quakerclean 624 MPC Quakerclean 680 VDA Quakerclean 830 BFF QH EXOMAX P 6411 QH EXOMAX 5378 QH EXOMAX 5380 QH EXOMAX 5285 US QH EXOMAX 154 CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 48
Slide 48: QH EXOMAX 154
QH EXOMAX 154 CONFIDENTIAL, DO NOT DISTRIBUTE 49
Slide 49: Product Highlight – QH EXOMAX
Product Highlight – QH EXOMAX 154 Industry Benefits • Cleans water dilutable forming Overview fluids • Good for multi-metal applications QH EXOMAX 154 is a global alkaline liquid spray QH EXOMAX washer cleaner with 154 automotive OEM approvals. Customer Benefits • Excellent wetting and outstanding F
Slide 50: Recommendations for Use
Recommendations for Use • Designed for spray cleaning applications at 2-5% depending on soil load • Can be used in all stages of multi-stage washers • Good for high pressure • Temperature: Ambient-60°C • Contains no boron, silicates, or phosphates for less residue and waste treatment issues • Provid
Slide 51: Case Study 1
Case Study 1 ▪ An automotive site in the US was seeing overall success with the QH EXOMAX 5285-US which allowed Quaker Houghton to systematically eliminate competitor cleaners from the final cleaning stage ▪ Due to the higher cost of the QH EXOMAX 5285-US, there was resistance to convert the in-proc
Slide 52: Case Study 1 - Customer Application
Case Study 1- Customer Application In-Process washers Final washers ▪ Aluminum heads and ▪ Pre-assembly aluminum blocks with cast ▪ Larger central systems iron inserts ▪ Much longer dump cycles ▪ Cleaning off coolant and ▪ Extended RP for cast iron honing oils inserts ▪ Single stage washers, ▪ Ambie
Slide 53: Case Study 1 - Product requirements
Case Study 1 Product requirements ▪ Biostable ▪ Ambient cleaning (110°F) ▪ High-pressure/low foam ▪ Lower cost ▪ Multi-metal ▪ In-process rust protection, lower than QH EXOMAX 5285-US ▪ Boron free ▪ No triazine ▪ Sacrifice oil spitting ▪ Global availability CONFIDENTIAL, DO NOT DISTRIBUTE 54 ©2019 Q
Slide 54: Case Study 1 - Results
Case Study 1 Results- Development of QH EXOMAX 154: ▪ Plants were recommended to maintain 3.5% concentration ▪ Cleaning performance was good (comments made that it was cleaning as well as the QH EXOMAX 5285-US) ▪ pH drifts were eliminated ▪ No further foam issues ▪ No bio issues ▪ No rust issues ▪ U
Slide 55: Case Study Follow Up
Case Study 1 Follow Up: ▪ During the conversions to QH EXOMAX 154, customer began internal testing for compatibility of coolants and cleaners with their Loctite adhesive due to engine oil leaks occurring in higher mileage vehicles ▪ The results of the test showed most of the other cleaners to reduce
Slide 56: Case Study 2
Case Study 2 CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 57
Slide 57: QH EXOMAX 5285 US
QH EXOMAX 5285 US CONFIDENTIAL, DO NOT DISTRIBUTE 58 ©2021 Quaker Houghton. All Rights Reserved
Slide 58: Product Highlight – QH EXOMAX 5285 US
Product Highlight – QH EXOMAX 5285 US Industry Benefits • Cleans heavy to moderate Overview soils such as water dilutable forming fluids QH EXOMAX 5285-US is an alkaline liquid spray QH EXOMAX washer cleaner with 5285 US automotive OEM approvals. Customer Benefits • Excellent wetting and outstanding
Slide 59: Case Study 3
Case Study 3 Results: Below is a comparison of the total operating costs of the Opportunity: central washers for the last 29 months. The A major Automotive facility was interested in improving performance is shown in CPU to incorporate all of the the performance of two 10,000-gallon central washer c
Slide 60: Automotive Spray Cleaners
Automotive Spray Cleaners QUAKERCLEAN 624 CP ⬧ QUAKERCLEAN 624 MPC ⬧ QUAKERCLEAN 680 VDA CONFIDENTIAL, DO NOT DISTRIBUTE 61 ©2019 Quaker Houghton. All Rights Reserved
Slide 61: Product Highlight – QUAKERCLEAN CP
Product Highlight – QUAKERCLEAN® 624 CP Industry Benefits • Cleans semi-synthetic metal Overview removal soluble soils, such as; • HOCUT® brand QUAKERCLEAN® 624 CP is • QUAKERCOOL® brand a dual purpose, mild alkaline QUAKERCLEAN® liquid that simultaneously 624 CP cleans and protects metal surfaces i
Slide 62: Additional Product Information QUAKERCLEAN CP Approvals
Additional Product Information QUAKERCLEAN® 624 CP Approvals • In-process high pressure applications. • Hammelmann Pumps (>5K psi) • FANUC – Robot Specific • Excellent RP – (30-60 days) • ABB • Aluminum and Ferrous applications • Approved at automotive OEMs • GM • Ford • FCA • Toyota • Honda CONFIDE
Slide 63: Product Highlight – QUAKERCLEAN MPC
Product Highlight – QUAKERCLEAN® 624 MPC Industry Benefits • Cleans metal removal Overview soluble fluids, such as; • HOCUT® brand • QUAKERCOOL® brand QUAKERCLEAN® 624 MPC is a dual purpose, mild QUAKERCLEAN® alkaline liquid that 624 MPC simultaneously cleans and protects metal surfaces in a single
Slide 64: Additional Product Information QUAKERCLEAN MPC Approvals
Additional Product Information QUAKERCLEAN® 624 MPC Approvals • In-process cleaning applications for • Hammelmann pumps more aggressive soils • FANUC – Robot specific • Up to 2,500 psi • ABB • Excellent RP – (30-60 days) • Aluminum and Ferrous applications • Oil-rejection technology • Approved at au
Slide 65: Product Highlight – QUAKERCLEAN VDA
Product Highlight – QUAKERCLEAN® 680 VDA Industry Benefits • Cleans low viscosity metal Overview removal neat fluids, such as; • QUAKERCUT® brand • WIOLAN brand QUAKERCLEAN® 680 VDA is specifically designed for low- QUAKERCLEAN® residue and vacuum drying 680 VDA applications. Customer Benefits • Cle
Slide 66: QUAKERCLEAN 680 VDA – Vacuum Drying Applications
Complimentary Product Introduction - QUAKERCLEAN® 680 VDA – Vacuum Drying Applications • In-process cleaner designed for minimal residue. Specifically in vacuum drying applications. • Superior wetting, oil-rejection and rapid drying properties • BEST RP protection – (60 days) • Aluminum and Ferrous
Slide 67: Product Highlight – QH EXOMAX P 6411
Product Highlight – QH EXOMAX P 6411 Industry Benefits • Versatile, cleans and Overview protects ferrous and non- ferrous surfaces in a single step QUAKERCLEAN® 6830 BFF was specially developed for QH EXOMAX P applications that require 6411 vacuum drying, formulated to Customer Benefits dry quickly
Slide 68: Heat Treatment Cleaning
Heat Treatment Cleaning CONFIDENTIAL, DO NOT DISTRIBUTE 69 ©2021 Quaker Houghton. All Rights Reserved
Slide 69: QH offering
QH offering Adding value across the manufacturing value chain Rough Final Cleaning Heat Cleaning pre / Hard Grinding Grease Fill of Hot Forging Machining & & Metal Treatment Post Quench & Honing the bearing Soft Grinding protection PRE-QUENCHING CLEANING • Parts need to be cleaned before the quenchi
Slide 70: QH offering
QH offering Adding value across the manufacturing value chain Rough Final Cleaning Heat Cleaning pre / Hard Grinding Grease Fill of Hot Forging Machining & & Metal Treatment Post Quench & Honing the bearing Soft Grinding protection POST-QUENCHING CLEANING • Residue oils left on parts after quenching
Slide 71: Maintenance Cleaners
Maintenance Cleaners CONFIDENTIAL, DO NOT DISTRIBUTE 72 ©2021 Quaker Houghton. All Rights Reserved
Slide 72: Product Highlight – MTC-53
Product Highlight – MTC-53 Industry Benefits • Cleans semi-synthetic metal Overview removal soluble fluids • Used for cleaning out cleaner bath MTC-53 is a powerful, effective cleaner for machine MTC-53 tools and central coolant systems. Customer Benefits • Powerful detergent action • Fast acting •
Slide 73: Product Highlight – HOCUT SYM-C
Product Highlight – HOCUT® SYM-C Industry Benefits • Cleans and removes Overview soluble oils HOCUT® SYM-C is formulated to clean deposits HOCUT® SYM-C and residues off machines, coolant sumps, and coolant Customer Benefits • Outstanding cleaning capability distribution systems • Superior solvency •
Slide 74: Product Highlight – QH EXOMAX B 1311
Product Highlight – QH EXOMAX B 1311 Industry Benefits • Cleans moderate soil loads Overview (lighter viscosity lubes) QH EXOMAX B 1311 is a water-based maintenance QH EXOMAX cleaner formulated for B 1311 superior cleaning. Customer Benefits • Excellent cleaning Global formulation outside of • Worke
Slide 75: Product Highlight – QH EXOMAX F 1410
Product Highlight – QH EXOMAX F 1410 Industry Benefits • Cleans heavy duty soils Overview (greases, way lubes, thicker viscosity lubes) QH EXOMAX F 1410 is a general maintenance and QH EXOMAX floor cleaner that provides F 1410 excellent performance in a Customer Benefits variety of general • Effecti
Slide 76: Floor Cleaner Benchmarking
Floor Cleaner Benchmarking Competitor Cleaner 1 Competitor Cleaner 2 pH 9.5 pH 13 CONFIDENTIAL, FOR INTERNAL USE ONLY, DO NOT DISTRIBUTE 78 ©2021 Quaker Houghton. All Rights Reserved
Slide 77: Global Metalworking Cleaner Trends
Global Metalworking Cleaner Trends • Sustainability • Reduced consumption of cleaner, water and/or energy • Reduced EHS profile • Multi-Metal Compatibility • Increased requirements for both Aluminum and Ferrous compatibility • Approvals- Automotive and Aerospace • Global harmonization for product se
Slide 78: Thank You!
Thank You! 80 CONFIDENTIAL ©2024 Quaker Houghton. All Rights Reserved