Agilent Technologies, Inc. · NYSE:A

Agilent Technologies — Technical Presentation (June 2013)

61 slides from Agilent Technologies's technical presentation, Jun 27, 2013

Slide 2: Simulated Distillation Methods: Application to Petroleum Processes
Simulated Distillation Methods: Application to Petroleum Processes Dave Grudoski weMeasureIt, Inc. Houston June 27, 2013 © 2000, 2001 weMeasureIt inc
Slide 3: An Overview of Simulated Distillation Methods and Their Application to Petroleum Processes
An Overview of Simulated Distillation Methods and Their Application to Petroleum Processes There are a number of ASTM Simulated Distillation Methods that overlap in boiling range and scope. In this presentation we discuss the ASTM methods and their merits and challenges for the analysis of petroleum
Slide 4: Refinery Operational Controls
Refinery Operational Controls Temperature/Pressure/Flow Measurements Cut Point Temperature Cat. Avg. Bed Temp. Recycle Pressure Volumetric Product Yield The Boiling Point is the single control variable consistently applied across all refinery process streams and operations. © 2000, 2001 weMeasureIt
Slide 5: The Value of Process Measurements
The Value of Process Measurements Applications Realized Savings Crude Unit Monitoring $800K/Mo LPG Stream Quality $3MM Year Effluent Monitoring $200K/Day FCC Operations Hydrocracking Operations $5MM Year © 2000, 2001 weMeasureIt inc
Slide 6: The Value of Accurate Cut Points
The Value of Accurate Cut Points Shift of 10°F in Yield (Wt %) Cutpoint is worth $10.00/BBL Boiling Point (°F) © 2000, 2001 weMeasureIt inc
Slide 7: What is True Boiling Point
What is True Boiling Point TBP is term describing the analytical results obtained from the distillation of stabilized crude petroleum to a final cut temperature of 400°C Atmospheric Equivalent Temperature (AET). … This test method details procedures for the production of a liquified gas, distillate
Slide 8: True Boiling Point
True Boiling Point TBP Curve for Distillation of a Whole Crude 1400 1200 1000 TBP* (F) 800 850-1000 F 650-850 F 600 500-650 F 400 350-500 F 200 300-350 F 0 0 10 20 30 40 50 60 70 80 90 100 YIELD FROM CRUDE** (VOL%) © 2000, 2001 weMeasureIt inc
Slide 9: True Boiling Point and SimDis of a Whole Crude
True Boiling Point and SimDis of a Whole Crude © 2000, 2001 weMeasureIt inc
Slide 10: SimDis
SimDis SimDis (short for Simulated Distillation) is a standardized chromatographic method which models the distillation curve of a hydrocarbon mixture and converts retention time to Boiling Point. American Standards and Testing Methods (ASTM)currently uses 6 SimDis methods for a variety of sample ty
Slide 11: SimDis-GC
SimDis-GC SimDis-Gas Chromatography partitions the sample based on the boiling points of the individual compounds n-C11 contained in the sample. Low boiling compounds (molecules) are eluted and characterized first followed by higher boiling compounds n-C20 n-C5 © 2000, 2001 weMeasureIt inc
Slide 12: Simulated Distillation
Simulated Distillation SIMDIS is a chromatographic procedure which translates retention time to boiling point…. © 2000, 2001 weMeasureIt inc
Slide 14: D2887 SIMDIS Yield % vs BP
D2887 SIMDIS Yield % vs BP 60% yield % occurs at 650°F Half a barrel of crude is directly Boiling point is the one usable as a distillate fuel common measurement applicable to all refining process streams Yield % (wt basis) SIMDIS information is essential in assigning value to crude and develop refi
Slide 15: A Chromatographic View of Distillate Fractions
A Chromatographic View of Distillate Fractions Naphtha/Gasoline Kero/Jet Yield (Wt %) Diesel Atmos. Gas Oil Vacuum Gas Oil Residum Boiling Point (°F) © 2000, 2001 weMeasureIt inc
Slide 16: Current ASTM SimDis Methods
Current ASTM SimDis Methods Active Standards: D2887-13 Standard Test Method for Boiling Range Distribution of Petroleum Fractions by Gas Chromatography D3710-95(2009) Standard Test Method for Boiling Range Distribution of Gasoline and Gasoline Fractions by Gas Chromatography D7096-10 Standard Test M
Slide 17: ASTM SimDis Methods
ASTM SimDis Methods ASTM Method BP Range (Carbon #) Application D3710 -162-260C (nC1-nC15) Naphthas, Gasolines D7096 -162-280C (nC1-nC16) Naphthas, Gasolines (expands 3710) D2887 -162-545C (nC1-nC44) Naphthas thru VGO D7213 100-615 C (nC7-nC60) Hvy Naphtha, Kerosene, Jet, Diesel D6352 174-715C (nC10
Slide 18: ASTM SimDis Methods
ASTM SimDis Methods ASTM Method BP Range (Carbon #) Application D3710 -259-500F (nC1-nC15) Naphthas, Gasolines D7096 -259-536F (nC1-nC16) Naphthas, Gasolines (expands 3710) D2887 -259-1000F (nC1-nC44) Naphthas thru VGO D7213 200-1100F (nC7-nC60) Hvy Naphtha, Kerosene, Jet, Diesel D6352 345-1292F (nC
Slide 19: ASTM D2887
ASTM D2887 Analysis of Naphthas, Kerosene, Jet, Diesel, VGO’s and HVGO’s with FBP<1000F Procedure: For non-viscous samples: Inject neat For viscous samples: Dilute sample with CS2 The sample must have a BP Range >100F Run in order: (Although Not a Requirement) Blank Calibration QC Reference (2X) © 2
Slide 20: ASTM D2887
ASTM D2887 Hardware Requirements: Oven with Cryo Cooling to -20C Oven with 390C upper temperature PTV or Cool-On-Column Inlet with 390C Temp FID Column- 100% polydimethylsiloxane with upper Temp of 390C 99.999% N2,He, or H Carrier Gas Method Requirements: Calibration Run (nC3-nC44) (Maps Carbon Numb
Slide 21: D2887 SimDis Calibration Mix
D2887 SimDis Calibration Mix nC10 nC20 nC30 -44F nC3 1013F nC44 © 2000, 2001 weMeasureIt inc
Slide 22: D2887 SimDis of Crude Fractions
D2887 SimDis of Crude Fractions SimDis Analysis of: 1. Straight Run Gasoline 2. Kerosene 3. Jet 4. Diesel © 2000, 2001 weMeasureIt inc
Slide 24: D2887 Analysis of a Reformer
D2887 Analysis of a Reformer SimDis Analysis of: Reforming Process which converts low octane components to high octane compounds 1. Reformer Feed: Alkanes and Isoparaffins 2. Reformer Product: Aromatics © 2000, 2001 weMeasureIt inc
Slide 25: D2887 Analysis of a Hydrocracker
D2887 Analysis of a Hydrocracker SimDis Analysis of: Hydrocracker Process which converts Gas Oils to Gasoline and Jet fuel Blending components Hydrocracker Feed Hydrocracker Whole Liquid Product Increasing Boiling Point © 2000, 2001 weMeasureIt inc
Slide 26: ASTM D7500
ASTM D7500 Analysis of Lube Oils, VGO’s and HVGO’s with FBP<1000F Procedure: Dilute the Sample to 1-3% solution with CS2 Run in order: (Although Not a Requirement) Blank Calibration QC Reference © 2000, 2001 weMeasureIt inc
Slide 27: ASTM 7500
ASTM 7500 Hardware Requirements: Oven with 430C upper temperature PTV or Cool-On-Column Inlet with 430Temp FID Column- 100% polydimethylsiloxane with upper Temp of 430C 99.999% N2,He, or H Carrier Gas Method Requirements: Calibration Run (nC3-nC110) (Maps Carbon Number Retention Time Axis to BP Axis
Slide 31: ASTM D7169
ASTM D7169 Analysis of Whole Crudes, Residua and other partially eluted samples Procedure: Dilute 0.02 g sample with 10 ml CS2 Inject Diluted Sample Run in order: Blank (and blanks after every sample) Calibration QC Reference (2X) © 2000, 2001 weMeasureIt inc
Slide 32: ASTM D7169
ASTM D7169 Hardware Requirements: Oven with Cryo Cooling to -20C Oven with 425C upper temperature PTV or Cool-On-Column Inlet with 425C Temp FID Column- 100% polydimethylsiloxane with upper Temp of 435C 99.999% N2,He, or H Carrier Gas © 2000, 2001 weMeasureIt inc
Slide 33: ASTM D7169
ASTM D7169 Method Requirements: Calibration Run (nC3-nC100) (Maps Carbon Number Retention Time Axis to BP Axis) Blank Run (determines EOR Baseline) Reference Oil 5010 -QC Reference (sets the Carbon Response Factor for Yield Recovery Calculations) © 2000, 2001 weMeasureIt inc
Slide 37: Fingerprinting Methods
Fingerprinting Methods Analytical Fingerprinting refers to the characterization of a sample by the use of techniques which use features obtained from the analysis to distinguish differences and similarities among samples and sample types. These methods are generally used to verify specification comp
Slide 38: Fingerprint Example
Fingerprint Example Hydrocarbons from a Pipeline Knockout Pots © 2000, 2001 weMeasureIt inc
Slide 39: Fingerprint Example
Fingerprint Example ****** Sorted Matches ******** 10 10.000 RED DYE DIESEL 1 0.0858 Unknown-2 *********************************** * 0 0.0814 Unknown-1 4 0.0418 Calibration 2 0.0417 C7-18+C20 w nC44WAX 3 0.0301 C7-18+C20 w nC44WAX 9 0.0297 Unknown-3 11 0.0251 Unknown-4 8 0.0250 No Injection Blank 5
Slide 40: Fingerprint Example
Fingerprint Example Red Dye Diesel when removed from the Sample shows © 2000, 2001 weMeasureIt inc another diesel and a gasoline as contaminants
Slide 41: Crude Oil Signature Library
Crude Oil Signature Library Reference Crude Oil Library © 2000, 2001 weMeasureIt inc
Slide 42: 2D Map of the Sample Universe
2D Map of the Sample Universe This plot presents a visualization in a 2D mathematical space of the chromatographic profiles for 1650 samples including 200 crude oils © 2000, 2001 weMeasureIt inc
Slide 43: Identification and Extraction of Similar Samples-Crude Oils
Identification and Extraction of Similar Samples-Crude Oils Here we show the utility of our approach to automatically extract the samples from the data base having the greatest © 2000, 2001 similarity weMeasureIt inc to the source sample
Slide 44: Identification and Extraction of Similar Samples-Naphthas
Identification and Extraction of Similar Samples-Naphthas Here we show the utility of our approach to automatically extract the samples from the data base having the greatest © 2000, 2001 similarity weMeasureIt inc to the source sample
Slide 58: Crude Oil Signature
Crude Oil Signature These Signatures (also often referred to as “Fingerprints”) map the crude composition to an invariant Boiling Point scale © 2000, 2001 weMeasureIt inc
Slide 60: Crude Oil Characterization
Crude Oil Characterization Crude A (Asian) Crude C (South American) Crude B (Mid-East) Carbon and Sulfur Distributions in Crude Oils © 2000, 2001 weMeasureIt inc

Agilent Technologies — Technical Presentation (June 2013) on 6ix

Agilent Technologies — Technical Presentation (June 2013)

Slide 1: Agilent SimDis Applications

Slide 2: Simulated Distillation Methods: Application to Petroleum Processes

Slide 3: An Overview of Simulated Distillation Methods and Their Application to Petroleum Processes

Slide 4: Refinery Operational Controls

Slide 5: The Value of Process Measurements

Slide 6: The Value of Accurate Cut Points

Slide 7: What is True Boiling Point

Slide 8: True Boiling Point

Slide 9: True Boiling Point and SimDis of a Whole Crude

Slide 10: SimDis

Slide 11: SimDis-GC

Slide 12: Simulated Distillation

Slide 13: D2887 SIMDIS

Slide 14: D2887 SIMDIS Yield % vs BP

Slide 15: A Chromatographic View of Distillate Fractions

Slide 16: Current ASTM SimDis Methods

Slide 17: ASTM SimDis Methods

Slide 18: ASTM SimDis Methods

Slide 19: ASTM D2887

Slide 20: ASTM D2887

Slide 21: D2887 SimDis Calibration Mix

Slide 22: D2887 SimDis of Crude Fractions

Slide 23: D2887 Analysis of Crude Unit Side Cuts

Slide 24: D2887 Analysis of a Reformer

Slide 25: D2887 Analysis of a Hydrocracker

Slide 26: ASTM D7500

Slide 27: ASTM 7500

Slide 28: Hi-Temp Blank

Slide 29: Hi-Temp SimDis Calibration

Slide 30: ASTM 7500: Time to Temp

Slide 31: ASTM D7169

Slide 32: ASTM D7169

Slide 33: ASTM D7169

Slide 34: ASTM D7169: Crude Oil

Slide 35: ASTM D7169: Atmospheric Residua

Slide 36: D7169 of Whole Crude

Slide 37: Fingerprinting Methods

Slide 38: Fingerprint Example

Slide 39: Fingerprint Example

Slide 40: Fingerprint Example

Slide 41: Crude Oil Signature Library

Slide 42: 2D Map of the Sample Universe

Slide 43: Identification and Extraction of Similar Samples-Crude Oils

Slide 44: Identification and Extraction of Similar Samples-Naphthas

Slide 45: Agilent SimDis

Slide 46: Agilent SimDis

Slide 47: Agilent SimDis

Slide 48: Agilent SimDis

Slide 49: Agilent SimDis Calibration

Slide 50: Agilent SimDis Calibration

Slide 51: Agilent SimDis QC Reference

Slide 52: Agilent SimDis Calibration

Slide 53: Agilent SimDis Engineering Report

Slide 54: Agilent SimDis Signature Report

Slide 55: Agilent SimDis Calibration Report

Slide 56: Agilent SimDis Calibration Report

Slide 57: Thank You for your time and attention

Slide 58: Crude Oil Signature

Slide 59: Crude Oil Fingerprinting

Slide 60: Crude Oil Characterization

Slide 61: Hi-Temp Calibration